36. The Van’t Hoff’s factor for aqueous 0.001 M mono basic acid, HA is 1.08. The ionization constant of acid will be:
(a)
(b)
(c)
(d)
Answer:
(a)
Explanation:
For a weak monobasic acid, , so , meaning . The dissociation constant .
37. At what temperature, R.M.S. speed of gas molecules will be double the value at N.T.P.?
(a) 273 K
(b) 546 K
(c) 1092 K
(d) 2184 K
Answer:
(c) 1092 K
Explanation:
The root mean square speed () is directly proportional to . To double the speed, the absolute temperature must increase by a factor of 4. Since N.T.P. is 273 K, the new temperature is .
38. The temperature coefficient of cell, is equal to:
(a)
(b)
(c)
(d)
Answer:
(a) $\frac{\Delta S^{\circ}}{nF}$
Explanation:
From thermodynamic relations, the entropy change of an electrochemical cell is given by . Rearranging this gives the temperature coefficient as .
39. , on strong heating at , produces :
(a) Pyro phosphoric acid
(b) Meta phosphoric acid
(c) Tri poly phosphoric acid
(d) Tetra poly phosphoric acid
Answer:
(b) Meta phosphoric acid
Explanation:
When orthophosphoric acid () is strongly heated to around 316-320°C, it loses molecules of water to yield metaphosphoric acid .
40. The ion having cyclic structure is:
(a)
(b)
(c)
(d)
Answer:
(c) $Se_4^{2+}$
Explanation:
The (and ) cations exist as square planar cyclic aromatic rings containing 6 pi electrons (following Hückel’s rule where ).