31. Which of the following statement is true about chemisorption ?

(a) It is reversible in nature

(b) It usually occurs at low temperature

(c) It is highly specific

(d) It involves Vander Waals forces

Answer:

Explanation:

32. Under normal conditions, which of the following halide do not show F-centres ?

(a) AgCl

(b) LiCl

(c) NaCl

(d) KCl

Answer:

Explanation:

33. Joule-Thomson coefficient is defined as:

(a) (δHδP)T(\frac{\delta H}{\delta P})_T

(b) (δHδT)p(\frac{\delta H}{\delta T})_p

(c) (δPδT)H(\frac{\delta P}{\delta T})_H

(d) (δTδP)H(\frac{\delta T}{\delta P})_H

Answer:

Explanation:

34. One mole of NaCl(s) on melting absorbed 30.5 kJ of heat and its entropy is increased by 28.8 JK128.8~JK^{-1}. What is melting point of NaCl ?

(a) 840 K

(b) 105.9 K

(c) 1059 K

(d) 100 K

Answer:

Explanation:

35. For equilibrium in closed vessel 2NH3(g)N2(g)+3H2(g)2NH_3(g) \rightleftharpoons N_2(g) + 3H_2(g), KpK_p is found 6 times of KcK_c. This is attained when T is: (given R=0.0821 L atm K1mole1R = 0.0821 \text{ L atm K}^{-1}\text{mole}^{-1})

(a) 73.08 K

(b) 29.8 K

(c) 36.5 K

(d) 59.6 K

Answer:

Explanation:

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